Coulomb explosion imaging of CH3I and CH2ClI photodissociation dynamics

Link:
Autor/in:
Erscheinungsjahr:
2018
Medientyp:
Text
Schlagworte:
  • Photodissociation
  • Dynamics
  • C-I bond
  • Quantum Chemistry
  • Potential Energy Surfaces
  • Reaction
  • Photodissociation
  • Dynamics
  • C-I bond
  • Quantum Chemistry
  • Potential Energy Surfaces
  • Reaction
Beschreibung:
  • The photodissociation dynamics of CH3I and CH2CII at 272 nm were investigated by time-resolved Coulomb explosion imaging, with an intense non-resonant 815nmprobe pulse. Fragment ion momenta over a widem/z range were recorded simultaneously by coupling a velocity map imaging spectrometer with a pixel imaging mass spectrometry camera. For both molecules, delay-dependent pump-probe features were assigned to ultraviolet-induced carbon-iodine bond cleavage followed by Coulomb explosion. Multi-mass imaging also allowed the sequential cleavage of both carbon-halogen bonds in CH2ClI to be investigated. Furthermore, delay-dependent relative fragment momenta of a pair of ions were directly determined using recoil-frame covariance analysis. These results are complementary to conventional velocity map imaging experiments and demonstrate the application of time-resolved Coulomb explosion imaging to photoinduced real-time molecular motion. Published by AIP Publishing.
Lizenz:
  • info:eu-repo/semantics/restrictedAccess
Quellsystem:
Forschungsinformationssystem der UHH

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oai:www.edit.fis.uni-hamburg.de:publications/0801535f-7831-4283-8bba-5a5761d8c2af