Performance of limestones laden with mixed salt solutions of Na2SO4-NaNO3 and Na2SO4-K2SO4

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Autor/in:
Erscheinungsjahr:
2013
Medientyp:
Text
Schlagworte:
  • Drying
  • Porous materials
  • Salt weathering
  • Conservation
  • Limestone
  • Historic Preservation
  • Drying
  • Porous materials
  • Salt weathering
  • Conservation
  • Limestone
  • Historic Preservation
Beschreibung:
  • The behaviour of two types of limestones having a different porosity, Maastricht and Euville limestone, laden with aqueous solutions of equimolar mixtures of sodium sulphate/sodium nitrate or sodium sulphate/potassium sulphate was investigated. At 50 \% RH, the efflorescences on Maastricht samples during the first 30 h of drying consisted of similar amounts of thenardite and darapskite in case of an equimolar mixture of sodium sulphate/sodium nitrate while those on Euville samples under the same conditions contained mainly darapskite. After drying at 20 A degrees C and 85 \% RH, thenardite, formed through the precipitation and dehydration of mirabilite, was mostly detected in the efflorescences on both Maastricht and Euville samples. Re-wetting by increasing the RH from 50 to 85 \% resulted in substantial damage on Maastricht stone laden with an equimolar mixture of sodium sulphate/sodium nitrate as a consequence of high supersaturation of mirabilite. In case of a contamination with equimolar amounts of sodium sulphate and potassium sulphate, the efflorescence on both limestones during drying at 50 \% RH contained predominantly aphthitalite. The observed crystallisation behaviour is compared to the theoretical behaviour. The results indicate a strong influence of stone properties on the crystallisation behaviour of salt mixtures.
Lizenz:
  • info:eu-repo/semantics/restrictedAccess
Quellsystem:
Forschungsinformationssystem der UHH

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oai:www.edit.fis.uni-hamburg.de:publications/3516c09e-63ac-4fd8-ada1-b9efa34fc065