An unstable paramagnetic isopolyoxomolybdate intermediate non-homogeneously reduced at different sites and trapped in a host based on chemical adaptability

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Autor/in:
Erscheinungsjahr:
2013
Medientyp:
Text
Schlagworte:
  • Self assembly
  • Surface active agents
  • Polyoxometalate POM
  • Ligands
  • Synthesis (Chemical)
  • Negative Ions
  • density functional calculations
  • host-guest systems
  • polyoxometalates
  • electronic structure
  • trapping of intermediates
  • Self assembly
  • Surface active agents
  • Polyoxometalate POM
  • Ligands
  • Synthesis (Chemical)
  • Negative Ions
Beschreibung:
  • Stabilize me: A metal oxide host with a trapped unstable {Mo 36}-type polyoxomolybdate guest exhibits independent reduced diamagnetic building blocks and paramagnetic centers (both types with colors other than the dark blue of the Mo centers). The guest in such systems is stabilized especially by a hydrogen-bond network between the core and the shell. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Lizenz:
  • info:eu-repo/semantics/restrictedAccess
Quellsystem:
Forschungsinformationssystem der UHH
Interne Metadaten
Quelldatensatz
oai:www.edit.fis.uni-hamburg.de:publications/fd1fc3d9-6877-4bbd-b478-81e8db8016ba