Schutzgruppen-freie Totalsynthesen von Rubrolid R und S , Protecting Group Free Total Syntheses of Rubrolide R and S

Link:
Autor/in:
Erscheinungsjahr:
2017
Medientyp:
Text
Schlagworte:
  • Aldol reactions
  • Antiviral agents
  • Cross-coupling
  • Natural products
  • Total synthesis
Beschreibung:
  • The two marine natural products rubrolide R (1) and S (2) were synthesised in only three linear steps starting from commercially available tetronic acid without using protecting-group chemistry. Key steps in the syntheses were the Pd-catalysed Suzuki–Miyaura cross-coupling followed by a vinylogous aldol condensation. Both compounds have been tested for their antibiotic and antiviral activities. At a concentration of 10 µm rubrolide R (1) and S (2), a 2-log and 1.5-log reduction in virus titre has been detected for a seasonal influenza virus (H3N2) and the pandemic swine influenza virus (pH1N1), respectively.
Lizenz:
  • info:eu-repo/semantics/closedAccess
Quellsystem:
Forschungsinformationssystem der UHH

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oai:www.edit.fis.uni-hamburg.de:publications/2a4aefcd-f715-4d8c-88f7-684a1c5e2a98