We build two-dimensional quantum field theories on spin surfaces starting from theories on oriented surfaces with networks of topological defect lines and junctions. The construction uses a combinatorial description of the spin structure in terms of a triangulation equipped with extra data. The amplitude for the spin surfaces is defined to be the amplitude for the underlying oriented surface equipped with a defect network dual to the triangulation. Independence of the triangulation and of the other choices follows if the line defect and junctions are obtained from a Δ-separable Frobenius algebra with involutive Nakayama automorphism in the monoidal category of topological defects. For rational conformal field theory, we can give a more explicit description of the defect category, and we work out two examples related to free fermions in detail: the Ising model and the so(n) WZW model at level 1.