Crystal structure of 2-pentyloxybenzamide

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Autor/in:
Erscheinungsjahr:
2014
Medientyp:
Text
Schlagworte:
  • Dimers
  • Capsules
  • Aromatic thioamides
  • Steroids
  • Athletes
  • Sports
  • hydrogen bonding.
  • crystal structure
  • 2-alkoxybenzamide
  • Dimers
  • Capsules
  • Aromatic thioamides
  • Steroids
  • Athletes
  • Sports
Beschreibung:
  • In the title molecule, C12H17NO2, the amide NH2 group is oriented toward the pentyloxy substituent and an intramolecular N-H⋯O hydrogen bond is formed with the pentyloxy O atom. The benzene ring forms dihedral angles of 2.93(2) and 5.60(2)° with the amide group and the pentyloxy group mean planes, respectively. In the crystal, molecules are linked by pairs of N-H⋯O hydrogen bonds, forming inversion dimers with their molecular planes parallel, but at an offset of 0.45(1)Å to each other. These dimers are ordered into two types of symmetry-related columns extended along the a axis, with the mean plane of one set of dimers in a column approximately parallel to (121) and the other in a column approximately parallel to (1-21). The two planes form a dihedral angle of 85.31(2)°, and are linked via C-H⋯O hydrogen bonds and C-H⋯π interactions, forming a three-dimensional framework structure.
Lizenz:
  • info:eu-repo/semantics/restrictedAccess
Quellsystem:
Forschungsinformationssystem der UHH

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Quelldatensatz
oai:www.edit.fis.uni-hamburg.de:publications/bc542f0d-23d2-4984-9108-f111f46a62ce