Formation of trichlorosilyl-substituted carbon-centered stable radicals through the use of π-accepting carbenes

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Autor/in:
Erscheinungsjahr:
2013
Medientyp:
Text
Schlagworte:
  • Germanium
  • Ligands
  • Ge Sn
  • Silicon
  • Silanes
  • density functional calculations
  • radicals
  • carbenes
  • radical-chlorine interactions
  • EPR spectroscopy
  • Germanium
  • Ligands
  • Ge Sn
  • Silicon
  • Silanes
Beschreibung:
  • A radical change: Cyclic alkyl(amino) carbenes formed zwitterionic adducts with SiCl4, which were further converted into carbon-centered stable radicals by changing the donor-acceptor C→Si coordinate bond into a C-Si covalent bond through a KC8 reduction. As the carbon radical site was directly bonded to a SiCl3 unit, a radical center that is right next to an acceptor has been generated. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Lizenz:
  • info:eu-repo/semantics/restrictedAccess
Quellsystem:
Forschungsinformationssystem der UHH
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oai:www.edit.fis.uni-hamburg.de:publications/8c1b2b5f-7825-4b9b-a1f7-a3888fc10a7b