Giant pores in a chromium 2,6-Naphthalenedicarboxylate Open- Framework structure with MIL-101 topology

Link:
Autor/in:
Erscheinungsjahr:
2009
Medientyp:
Text
Schlagworte:
  • Organometallics
  • Organic polymers
  • Imidazolate frameworks
  • Ligands
  • Crystal Structure
  • Solvothermal synthesis
  • Structure simulation
  • Mesoporous materials
  • Metal-organic frameworks
  • High-throughput methods
  • Organometallics
  • Organic polymers
  • Imidazolate frameworks
  • Ligands
  • Crystal Structure
Beschreibung:
  • Large, larger,... Replacement of 1,4-benzenedicarboxylate by 2,6-naphthalenedicarboxylate in the MIL-101 structure leads to an isoreticular mesoporous framework containing cages with diameters of 39 and 46 Å. High-throughput methods are employed to determine appropriate reaction conditions. The microcrystalline compound is characterized by molecular simulation techniques, powder X-ray diffraction, N2-sorption, and TEM investigations. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.
Lizenz:
  • info:eu-repo/semantics/closedAccess
Quellsystem:
Forschungsinformationssystem der UHH
Interne Metadaten
Quelldatensatz
oai:www.edit.fis.uni-hamburg.de:publications/f1f3a47a-587d-403b-95d0-0f3b0bcf115f