A spherical 24 butyrate aggregate with a hydrophobic cavity in a capsule with flexible pores: Confinement effects and uptake-release equilibria at elevated temperatures

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Erscheinungsjahr:
2009
Medientyp:
Text
Schlagworte:
  • Self assembly
  • Surface active agents
  • Polyoxometalate POM
  • Ligands
  • Synthesis (Chemical)
  • Negative Ions
  • Polyoxometalates
  • Confinement effect
  • Hydrophobic effect
  • Porous capsules
  • NMR spectroscopy
  • Self assembly
  • Surface active agents
  • Polyoxometalate POM
  • Ligands
  • Synthesis (Chemical)
  • Negative Ions
Beschreibung:
  • Forced interaction: The encapsulation of a large assembly of organic species - the 24 butyrate unit, which exhibits a remarkable central spherical hydrophobic cavity spanned by 72 H atoms - in a porous capsule (see picture) leads to interesting interactions between the butyrates under the confined conditions. The quarantine for the guests is lifted upon temperature increase: guests can easily leave and return. © 2009 Wiley-VCH Verlag.
Lizenz:
  • info:eu-repo/semantics/closedAccess
Quellsystem:
Forschungsinformationssystem der UHH
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Quelldatensatz
oai:www.edit.fis.uni-hamburg.de:publications/0121e29d-fcba-4d25-bde7-b0fe61d2422d