Transitions between spin polarized and spin singlet incompressible ground state of quantum Hall systems at filling factor 2/3 are studied by means of exact diagonalization with eight electrons. We observe a stable exactly half–polarized state becoming the absolute ground state around the transition point. This might be a candidate for the anomaly observed during the transition in optical experiments. The state reacts strongly to magnetic inhomogeneities but it prefers stripe–like spin structures to formation of domains.