Synthesis and Catalysis of Anionic Amido Iron(II) Complexes

Low-coordinate, open-shell 3d metal complexes have attracted great attention due to their critical role in several catalytic transformations but have been notoriously difficult to prepare and study due to their high lability. Here, we report the synthesis of a heteroleptic tri-coordinate amidoferrate that displays high catalytic activity in the regioselective hydrosilylation of alkenes.