Bromidovanadium(II, III, and IV) complexes

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Autor/in:
Erscheinungsjahr:
2013
Medientyp:
Text
Schlagworte:
  • Vanadium
  • Vanadium compounds
  • Ethylene polymerization
  • Polymerization
  • Ethylene
  • Ligands
  • Vanadium
  • Vanadium compounds
  • Ethylene polymerization
  • Polymerization
  • Ethylene
  • Ligands
  • Benzimidazolyl/Pyridyl-dithiahexane
  • Trithiacyclononane
  • Bromidovanadium
  • L-edge XAS
  • K-edge XAS
Beschreibung:
  • The bromidovanadium complexes cis-[VIIBr2(bith)] (1) [bith = 1,6-bis(2-benzimidazolyl)-2,5-dithiahexane], cis-[VIIBr 2(pth)] (2a) [pth = 1,6-bis(2-pyridyl)-2,5-dithiahexane], cis-[V IIIBr2(pth)]Br (2b), trans-[VIIBr 2(tmeda)2] (3) (tmeda = tetramethylethylenediamine), fac-[VIIIBr3(9S3)] (4) (9S3 = 1, 4, 7-trithiacyclononane), mer-[VIIIBr3(thf)3] (5) (thf = tetrahydrofurane), and trans-[VIVOBr2(thf) 2H2O] (6) were prepared and characterized by, inter alia, XRD (5, 6), K-edge XAS (3, 4) or L-edge XAS (2a, 2b). The complexes are also addressed in the context of the potential of halogenidovanadium compounds in catalytically conducted reactions, including biogenic processes. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Lizenz:
  • info:eu-repo/semantics/restrictedAccess
Quellsystem:
Forschungsinformationssystem der UHH
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oai:www.edit.fis.uni-hamburg.de:publications/d71c14bd-0299-4bc0-b2bb-f04690cc2fd6