Theoretical Description of Attosecond X-ray Absorption Spectroscopy of Frenkel Exciton Dynamics

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Autor/in:
Erscheinungsjahr:
2023
Medientyp:
Text
Schlagworte:
  • coherent electron dynamics
  • attosecond spectroscopy
  • X-ray absorption spectroscopy
  • energy transfer
  • Frenkel excitons
Beschreibung:
  • Frenkel excitons are responsible for the transport of light energy in many molecular systems. Coherent electron dynamics govern the initial stage of Frenkel-exciton transfer. Capability to follow coherent exciton dynamics in real time will help to reveal their actual contribution to the efficiency of light-harvesting. Attosecond X-ray pulses are the tool with the necessary temporal resolution to resolve pure electronic processes with atomic sensitivity. We describe how attosecond X-ray pulses can probe coherent electronic processes during Frenkel-exciton transport in molecular aggregates. We analyze time-resolved absorption cross section taking broad spectral bandwidth of an attosecond pulse into account. We demonstrate that attosecond X-ray absorption spectra can reveal delocalization degree of coherent exciton transfer dynamics.
Lizenzen:
  • info:eu-repo/semantics/openAccess
  • http://creativecommons.org/licenses/by/4.0/
Quellsystem:
Forschungsinformationssystem der UHH

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Quelldatensatz
oai:www.edit.fis.uni-hamburg.de:publications/1152cbb8-c860-46a7-91e6-c6599f010cba