Direct and real-time observation of hole transport dynamics in anatase TiO2 using X-ray free-electron laser

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Erscheinungsjahr:
2022
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Beschreibung:
  • Carrier dynamics affects photocatalytic systems, but direct and real-time observations in an element-specific and energy-level-specific manner are challenging. In this study, we demonstrate that the dynamics of photo-generated holes in metal oxides can be directly probed by using femtosecond X-ray absorption spectroscopy at an X-ray free-electron laser. We identify the energy level and life time of holes with a long life time (230 pico-seconds) in nano-crystal materials. We also observe that trapped holes show an energy distribution in the bandgap region with a formation time of 0.3 pico-seconds and a decay time of 8.0 pico-seconds at room temperature. We corroborate the dynamics of the electrons by using X-ray absorption spectroscopy at the metal L-edges in a consistent explanation with that of the holes. © 2022, The Author(s).
Lizenzen:
  • info:eu-repo/semantics/openAccess
  • http://creativecommons.org/licenses/by/4.0/
Quellsystem:
Forschungsinformationssystem der UHH
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oai:www.edit.fis.uni-hamburg.de:publications/3356f680-925b-4bff-bae2-ce2dedb2d573