Thermoelectric power factor of ternary single-crystalline Sb 2Te3- and Bi2Te3-based nanowires

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Erscheinungsjahr:
2013
Medientyp:
Text
Schlagworte:
  • Thermoelectricity
  • Thermoelectric equipment
  • Bismuth telluride
  • Thermoelectric Equipment
  • Thermal Conductivity
  • Thermoelectricity
  • Thermoelectric equipment
  • Bismuth telluride
  • Thermoelectric Equipment
  • Thermal Conductivity
Beschreibung:
  • Nanowires of bismuth antimony telluride and bismuth telluride selenide (Bi15Sb29Te56 and Bi38Te55Se7) were grown by template-based pulsed electrodeposition. The composition and the crystallinity of the nanowires were determined by high-resolution transmission electron microscopy. The thermoelectric properties (Seebeck coefficient and electrical conductivity) of single p- and n-type nanowires, with diameter 80 nm and 200 nm, respectively, were determined as a function of temperature before and during heating in a helium atmosphere up to 300 K along the growth direction of the nanowires. After additional annealing in a tellurium atmosphere at 525 K, significantly enhanced transport properties are observed. Bulk-like power factors are achieved. In Bi38Te55Se7 nanowires, the Seebeck coefficients increase to -115 mu V K-1 and the thermoelectric power factors increase to 2820 mu W K-2 m(-1) at room temperature. In Bi15Sb29Te56 nanowires, Seebeck coefficients of up to S = +156 mu V K-1 and power factors of up to 1750 mu W K-2 m(-1) are obtained at room temperature.
Lizenz:
  • info:eu-repo/semantics/restrictedAccess
Quellsystem:
Forschungsinformationssystem der UHH

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oai:www.edit.fis.uni-hamburg.de:publications/e1206a5d-d336-4e55-a4e6-5676ee716335