The direct oxidative diene cyclization and related reactions in natural product synthesis

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Autor/in:
Erscheinungsjahr:
2016
Medientyp:
Text
Schlagworte:
  • asymmetric synthesis
  • natural products
  • oxidation catalysis
  • tetrahydrofurans
  • total synthesis
Beschreibung:
  • The direct oxidative cyclization of 1,5-dienes is a valuable synthetic method for the (dia)stereoselective preparation of substituted tetrahydrofurans. Closely related reactions start from 5,6-dihydroxy or 5-hydroxyalkenes to generate similar products in a mechanisticallyanalogous manner. After a brief overview on the history of this group of transformations and a survey on mechanistic andstereochemical aspects, this review article provides a summary on applications in natural product synthesis. Moreover, current limitationsand future directions in this area of chemistry are discussed.
Lizenz:
  • info:eu-repo/semantics/openAccess
Quellsystem:
Forschungsinformationssystem der UHH

Interne Metadaten
Quelldatensatz
oai:www.edit.fis.uni-hamburg.de:publications/c0783453-7a8b-4f1d-8ae7-ee217ffce387